The Order of the Phoenix might betray Harry. They could be forced to make a difficult decision that Harry sees as a betrayal. For instance, if they sacrifice Harry's safety for the greater good without his consent. Harry, feeling abandoned, could then be swayed to join Voldemort.
It could be Ron. Ron has always had some insecurities. If those insecurities grow, he might betray Harry. For example, if he thinks Harry is getting too close to Hermione or if he feels overshadowed by Harry's abilities. This betrayal would push Harry towards Voldemort.
Hermione could be the one. Maybe she gets jealous of Harry's fame and power, and starts spreading lies about him, which leads to his betrayal. As a result, Harry feels so hurt that he turns to Voldemort.
The Ministry of Magic could be the ones to betray Harry. They might try to use Harry as a pawn in their political games, and when Harry realizes this, he loses faith in the so - called good side. Voldemort then takes advantage of Harry's disillusionment and convinces him to join.
Perhaps Harry is betrayed by the wizarding world as a whole. The Ministry of Magic wrongly accuses him of a serious crime. With no one to turn to, Voldemort approaches Harry. Voldemort shows Harry a world where he can be in control, instead of being at the mercy of those who have turned against him. So, Harry decides to join Voldemort out of desperation and a thirst for revenge against those who betrayed him.
In this fanfic, Harry might be betrayed by the Order of the Phoenix. They could have made a decision that endangered Harry's life without his knowledge. Feeling used and discarded, Harry runs away. Voldemort, through his Death Eaters, finds Harry and manipulates him. He tells Harry that he can give him a place where he will be respected and not betrayed again. Harry, still young and naive in some ways, falls for Voldemort's lies and joins him, leading to a very different kind of war in the wizarding world.
The main antagonist could be Dumbledore. Since Harry has joined Voldemort, Dumbledore would see Harry as a threat to the good of the wizarding world. Dumbledore would try to bring Harry back to the right side, and they would end up in conflict.
Snape could play a crucial role. Given his past with both Voldemort and his role at Hogwarts, he might be torn between his loyalty to Dumbledore's cause and his complex relationship with Harry. He could be the one who has to make a difficult decision when Harry starts to side with Voldemort. Additionally, Draco Malfoy could be involved. He might see Harry's change as an opportunity to gain more power within Voldemort's ranks, or he could be jealous of Harry's new - found position with the Dark Lord.
In a 'harry joins voldemort fanfiction', perhaps Harry discovers a dark secret about the wizarding world that makes him think Voldemort was right all along. It could be something about the Ministry of Magic being corrupt and Voldemort's way of ruling, although extreme, is the only solution. So he joins Voldemort to 'fix' the wizarding world.
Perhaps he was deceived. There might be a powerful dark wizard who managed to convince Harry that the dark side had a more 'just' cause. This wizard could have used false information about the history of the wizarding world and how the dark side was initially misjudged.
One possible plot could be that Harry is influenced by Voldemort's false promises. Maybe Voldemort offers to bring back Harry's parents in exchange for his loyalty. Harry, in a moment of weakness and longing, decides to join him. However, once he realizes Voldemort's true nature of deception and destruction, he has to find a way to break free from this dark alliance.
Perhaps Harry joins Voldemort out of a sense of hopelessness. After seeing so much destruction in the wizarding world, he might think that joining Voldemort is the only way to end the war quickly. However, he soon realizes that Voldemort's methods are too extreme and tries to find a way to turn things around from within the dark side.
Well, it could be that Evil Harry is actually a long - lost relative of Voldemort in this fanfiction. He discovers this connection and, feeling a sense of kinship with Voldemort's ideology of pure - blood supremacy, decides to join him. He then uses his skills at Hogwarts, like his knowledge of spells and potions, to enhance Voldemort's army. He might also be involved in turning some of his classmates to the dark side, creating a rift within Hogwarts between those who follow him and those who oppose Voldemort's new ally.