Garou from OPM might also work well. His ideology of being a 'human monster' and his constantly evolving strength could make him a formidable foe for Saitama. Their clash could be not only about physical strength but also about their different views on what it means to be a hero or a monster.
Another interesting concept is a crossover where the villains from the OPM world are a threat to Saitama's own world. Saitama then has to team up with the OPM heroes to fight back. This could lead to some really cool fight scenes and interactions between different characters.
Tornado of Terror would likely be one of the first to try and take on Evil Saitama. She's powerful and confident, but she would soon realize the extent of his power. Mumen Rider, despite being weak, would still stand up to Evil Saitama out of a sense of justice. He would be quickly defeated but his act of courage might inspire other heroes to step up.
A villain like Shigaraki would likely be interested in the power levels in the MCU fanfiction. He's always looking for ways to increase his own power, and seeing the various powerful artifacts and abilities in the MCU might give him some ideas. He could think about how he could use similar things in his own plans to take over the MHA world.
Yes, the OPM manga has come to an end. The creators completed the narrative, providing closure to the fans. Although some might have hoped for more, what was presented was a comprehensive and conclusive tale.
She might be initially scared but quickly regain her composure. Uraraka is a brave character. She would likely start looking for ways to escape, using her zero - gravity quirk to her advantage, like floating up to vents or disabling the villains' weapons if she can.
Shigaraki would likely be disgusted if the fanfic made him seem weak or less of a threat. He'd probably scratch at his neck in irritation. Dabi would be dismissive. He'd think fanfics are just a waste of time and not worthy of his attention. Toga, though, might be intrigued. If the fanfic had a lot of blood and gore in it, or if it focused on her relationships in an interesting way, she could be really into it.