A villain like Shigaraki would likely be interested in the power levels in the MCU fanfiction. He's always looking for ways to increase his own power, and seeing the various powerful artifacts and abilities in the MCU might give him some ideas. He could think about how he could use similar things in his own plans to take over the MHA world.
If the MHA characters were to react to a Mastermind fanfiction, some would be more accepting than others. Characters like Ochaco might find it really exciting. She's a fan of the heroes herself, so seeing different takes in fanfiction would be like getting a new perspective on the MHA world. However, characters like Shoto, who are more reserved, might be a bit hesitant. He might need some time to process what he's reading. But overall, it would be a very interesting scenario as it would show how the characters view different interpretations of their world.
Some characters would be shocked. For example, if the fanfiction had a really dark and unexpected Mastermind plot, like a hero turning out to be the mastermind of all the villains' plans, characters like Tsuyu would be very taken aback. She'd probably question the motives behind such a plot. Then there are characters like Denki. He might be more into it if it had some cool action scenes in the fanfiction, regardless of how out - of - the - blue the Mastermind storyline was. And Nejire would probably be super curious about the emotional depth of the characters in the fanfiction.
MHA characters might also be a bit jealous of some of the superpowers or unique abilities in other anime fanfiction. In their world, quirks are relatively well - defined, but in some other anime, there are really out - of - this - world powers. They could be in awe of the creativity and at the same time, try to figure out how they could incorporate some of those ideas into their own fighting styles. Like, if they read a fanfiction about a character who can manipulate time, they might start thinking about how they could use their quirks in a time - related way.
Bakugo might initially be in denial. He's always had a complex relationship with Izuku, and seeing him in such a state could shatter his world view. He might become more withdrawn or, on the contrary, be spurred into a violent rage against whoever was responsible.
Well, Bakugo might scoff at first. He'd probably think Batman is too brooding and not as straightforward as he likes his heroes. But then as he reads more of the fanfiction, he might grudgingly admit that Batman's detective skills are cool. Deku, on the other hand, would be super interested. He'd be analyzing every move Batman makes in the fanfiction, taking notes in his head about Batman's strategies and how they could be applied in his own hero work. Uraraka would be more focused on the relationships in the fanfiction. She'd be all 'aww' at the cute moments and feel for the characters when they're in trouble.
The Doomguy was once a marine. He was sent to Mars to investigate some strange happenings on a Union Aerospace Corporation (UAC) facility. The UAC had been messing around with teleportation technology and had accidentally opened portals to Hell. Doomguy found himself in the middle of a demonic invasion. His initial experiences on Mars were filled with fighting off hordes of demons, and this was just the start of his journey to become the ultimate demon - slayer.
It can start with mutual distrust. Doomguy is used to killing demons, and the female demon is afraid of him. But when they are forced into a situation where they have to rely on each other to survive, like being trapped in a small area surrounded by more powerful demons, they start to see each other in a new light. They begin to communicate, first out of necessity, and then gradually become more open with each other.
There's a fanfic called 'Doomguy in the Hidden Leaf'. In this one, Doomguy gets transported to the Naruto universe. It's interesting to see how he interacts with the different ninja clans, especially when his no - nonsense attitude clashes with the more traditional ways of the Leaf Village. It's a short but engaging read.