In a fanfiction where Ash joins Team Rocket, it could lead to some really interesting storylines. Ash has a lot of knowledge about Pokémon training that Team Rocket lacks. He could potentially teach them new techniques, but at the same time, his moral compass would be constantly at odds with their devious ways. Maybe he joins them because he's somehow tricked or he has his own secret plan to take them down from the inside. It would be a great opportunity to explore different aspects of his character and how he adapts to this new situation.
Pikachu would probably be very confused at first. It's used to fighting against Team Rocket, not being on their side. It might resist and try to zap Ash to snap him out of it.
Some of his more loyal Pokemon might try to resist the change. For example, Pikachu could use electric shocks to try and jolt Ash back to his senses. Pikachu has a strong bond with Ash and would be very confused and sad about his decision to join Team Rocket.
Well, if Ash joined Team Rocket, he'd probably bring a whole new dynamic. His skills as a trainer could be used in unexpected ways. Maybe he'd try to reform Team Rocket from the inside, using his kind heart and love for Pokémon to change their ways. He could also introduce new strategies for capturing Pokémon that are more ethical than Team Rocket's usual methods.
Well, one plot twist could be that Ash is actually a double agent. He pretends to join Team Rocket to gather information for the good guys. Maybe he discovers a big secret plan of Team Rocket, like they're planning to steal all the Pokeballs in a certain region. This would completely change the power dynamic and put Team Rocket on high alert.
Well, in such a fanfiction, Ash might start using Team Rocket's sneaky tactics. He could learn from them how to be more devious in catching Pokémon. For example, he might use their elaborate traps instead of his usual straightforward battles. This would be a huge change from his normal good - guy image.
Well, it could make for a really interesting fanfiction. Dawn joining Team Rocket would change the whole dynamic. Her Pokémon might not be too happy about it at first. She could bring new ideas to Team Rocket, since she has a different way of thinking compared to Jessie, James and Meowth. However, it's also possible that she would secretly be working against Team Rocket from the inside, trying to take them down while pretending to be one of them.
One possible storyline is that Dawn joins Team Rocket thinking it's a legitimate Pokémon training organization at first. But as she gets deeper into it, she discovers their true evil nature. Another could be that she is brainwashed by Team Rocket into joining them. Her friends then have to find a way to break the brainwashing. A third storyline could be that she joins willingly because she has some sort of vendetta against the Pokémon League and sees Team Rocket as a way to get revenge.
One possibility is that Ash joins Team Galactic under some sort of misunderstanding. Maybe he thinks they are a group with good intentions at first. Once he realizes their true nature, he has to figure out a way to escape or stop them. This could create a lot of tension and action - packed scenes in the fanfiction.