Well, if Serena joins Team Rocket in a fanfiction, she might bring a new dynamic. Maybe she's forced to join at first. She could use her skills in battles and her knowledge of Pokemon to help Team Rocket in their schemes, but secretly she could be planning to take them down from the inside.
In a fanfiction where Ash joins Team Rocket, it could lead to some really interesting storylines. Ash has a lot of knowledge about Pokémon training that Team Rocket lacks. He could potentially teach them new techniques, but at the same time, his moral compass would be constantly at odds with their devious ways. Maybe he joins them because he's somehow tricked or he has his own secret plan to take them down from the inside. It would be a great opportunity to explore different aspects of his character and how he adapts to this new situation.
One idea could be that Serena is initially deceived by Team Flare's false promises of a better world for Pokemon. She might see their flashy technology and think they can help her become a stronger trainer. But as she gets deeper into the team, she starts to realize their true, evil intentions, like stealing Pokemon for their own gain.
Well, if Misty joins Team Rocket in fanfiction, it would be a huge shock to the other characters. Her friends like Ash would be completely bewildered. Maybe she's been tricked into it somehow, like being deceived by Team Rocket's false promises. This could lead to some really interesting plot twists. For example, she might be used to set traps for Ash and the others, but deep down still have some good in her that causes internal conflict within Team Rocket.
Well, it could make for a really interesting fanfiction. Dawn joining Team Rocket would change the whole dynamic. Her Pokémon might not be too happy about it at first. She could bring new ideas to Team Rocket, since she has a different way of thinking compared to Jessie, James and Meowth. However, it's also possible that she would secretly be working against Team Rocket from the inside, trying to take them down while pretending to be one of them.
One possible storyline is that Dawn joins Team Rocket thinking it's a legitimate Pokémon training organization at first. But as she gets deeper into it, she discovers their true evil nature. Another could be that she is brainwashed by Team Rocket into joining them. Her friends then have to find a way to break the brainwashing. A third storyline could be that she joins willingly because she has some sort of vendetta against the Pokémon League and sees Team Rocket as a way to get revenge.
Well, if Ash joins Team Rocket in a fanfic, it would be a huge shift in the Pokemon world. His friends, like Misty and Brock, would be shocked. They might try to rescue him. Ash, on the other hand, could initially be attracted to the idea of a new adventure with Team Rocket. He could see them as underdogs in a way, always failing but still trying. But as time goes on, he'd start to see the problems with their way of doing things.
Maybe there's a rogue Pokemon trainer. This trainer is jealous of Dawn's skills and the attention she gets. When Dawn joins Team Rocket, this trainer sees it as a chance to expose her as a fraud. He or she then tries to stop Dawn and Team Rocket's activities, thinking that they are up to no good, which they are, but the trainer has his own self - centered motives.
Pikachu would probably be very confused at first. It's used to fighting against Team Rocket, not being on their side. It might resist and try to zap Ash to snap him out of it.