Sasuke could be an alternative. He has strong ninja skills and a deep understanding of the ninja world. His experiences have made him grow into a very capable person, and his Sharingan gives him an edge in combat and strategic planning.
Well, it depends on the specific fanfiction. Some fanfictions might explore alternate storylines where Naruto doesn't become the Hokage at all. Maybe he decides to pursue a different path in life, like focusing on being a teacher or an explorer. However, in a large number of fanfictions, he does achieve his goal of becoming the Hokage because it's such an iconic and desired outcome for fans who want to see his journey to the top in different ways.
Naruto himself could be a likely candidate. Given his strength, leadership skills, and his dream of uniting the ninja world, he would make a great 6th Hokage.
Yami remains alive in the manga. The author chose to keep Yami as an ongoing character to drive the story forward and interact with other characters in various scenarios.
As far as I know, Yami doesn't die in the manga. The story might have twists and turns, but that particular event hasn't happened yet. Maybe there are rumors or speculations, but based on the official storyline, no.
One plot idea could be Yami going on a solo mission to a mysterious and dangerous land. He has to face powerful new enemies and discover secrets about his own past. Another could be Yami training a young and inexperienced magic knight, sharing his unique combat and magic knowledge.
To write a believable characterisation of Yami, focus on his rough exterior but also his loyalty to his squad. Show his love for food, especially Japanese food. Also, don't forget his unique magic style and how he uses it in combat.