Toge Inumaki is important too. His special cursed speech ability makes him stand out. Also, the principal of the school, Masamichi Yaga, is likely to be important as he is in a position of authority and has an influence on Gojo and the other students. There could be other characters like the members of different clans that also play roles in the complex web of the story.
The students would probably be very excited. Percy has a lot of charisma and his tales of adventure would be really interesting. Some students might be a bit intimidated at first, but once they see his friendly side, they'd warm up to him quickly.
It's hard to pinpoint exactly where Gojo is at any given time in the manga. His whereabouts change as the story progresses and different scenarios unfold. It could be in a supernatural realm, a mission site, or interacting with other characters.