The plot mainly revolves around the protagonist who finds herself in the role of a villainess in a story. Instead of following the original doomed path of the villainess, she decides to change things and just live her life as best as she can in this new situation.
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Well, love and relationships are probably important themes. In many light novels, there are romantic elements, and in this one, the villainess might have a different approach to love compared to the typical heroine. Also, survival could be a theme. She has to find a way to 'live on' which implies she has to navigate through various challenges and obstacles in the story world.
Well, the themes include survival and adaptation. She has to adapt to the strange world she's in as a villainess and find ways to survive the various challenges, like dealing with other characters who might be hostile towards her. And love is a big theme too. She may fall in love or have to deal with the love interests of other characters, which can be really complicated and interesting.
The side characters can also be really interesting. For example, the villainess's maids or servants. Their loyalty or lack thereof to the villainess can create interesting sub - plots. Also, any rival characters, like other noble ladies who might be competing with the villainess in terms of status or the affections of a certain character, are likely to be engaging.
Definitely the protagonist. She's in a tough situation, being a villainess, but she tries to make the best of it. Her character development is fascinating. Then there are the characters who oppose her. They add conflict to the story and their reasons for being against her can be quite intriguing. And the friends or allies she might make along the way are also interesting, as they support her in unexpected ways.
The main themes in 'the villainess just wants to live in peace novel' are likely to be survival and peace. The character is in a situation where she has to find a way to survive in a world that might be hostile to her because of her 'villainess' label. Peace is what she desires, so it's a major theme. Additionally, there could be a theme of identity. She has to redefine who she is and show that she's not the typical villainess, which is also an important aspect of the story.
It really depends on the specific plot and character development in the manhwa. Sometimes it happens early on, and in other cases, it might take a while.
It's a complex tale of a female character who finds herself in a challenging relationship with a tyrant. There are lots of twists and turns along the way.