Toga could be an ally. Since she has her own complex relationship with the idea of heroes and villains, she might find Deku's transformation interesting. She could provide some of her unique skills, like shape - shifting, to help Deku in his villainous plans. Additionally, Twice might also join them because of his loyalty to Toga and his own sense of being an outcast in the hero world.
In this fanfiction, Deku's character development could be quite complex. Going back in time, he may initially be overconfident because he thinks he knows what's going to happen. But as he realizes that changing the past has unforeseen consequences, he becomes more cautious. He also might develop a deeper understanding of his friends and their potential, as he gets to see them at an earlier stage. He could start mentoring some of them, which would in turn make him more responsible and mature as a character.
Naruto's outgoing and boisterous personality would make Deku more confident. He would probably be more upfront and less shy. Naruto's strong sense of justice would also intensify Deku's already existing desire to help others.
The main differences are in their expressions and some minor details of personality. In the manga, Deku might seem a bit more intense, while in the anime, he's sometimes presented a bit softer.
Todoroki can start by simply being there for Deku. Just sitting with him in silence when Deku doesn't feel like talking. It shows that he's not alone. Also, Todoroki can share his own struggles. Since he has his own complex family situation, he can relate to feeling down sometimes. This can make Deku feel that his problems are not unique and that it's okay to not be okay.
In some fanfictions, Bakugo can become more empathetic. For example, if he experiences a situation where he realizes the pain he's caused Deku over the years. His aggressive nature might soften as he starts to understand Deku better. Deku, on the other hand, could become more assertive. Instead of always being the timid one, he might stand up to Bakugo more firmly in fanfiction scenarios.
Deku might be completely shocked at first. Since Bakugou has always been so aggressive towards him, he would never expect such a confession. He might just stand there, mouth agape, not knowing what to say.
His friends could come to the rescue. Bakugo, for instance, might use his explosive power to break into Toga's hideout. He's always been competitive with Deku, but he also cares about him deeply.