One great 'Muichiro x Reader' fanfiction is 'A Meeting in the Mist'. It beautifully captures Muichiro's somewhat aloof nature while gradually developing a sweet relationship with the reader. The descriptive language used really makes you feel like you're in the Demon Slayer world with them.
One idea could be a rengoku fanfic where he trains a new group of young slayers. It could focus on his unique teaching methods and how he instills his values in them.
Tanjiro would be a great character to pair with rengoku. Their different personalities could create an interesting interaction. Tanjiro's kind - hearted nature and rengoku's fiery determination could lead to some great storylines.