Yes, Ned is part of the Spider-Man comic universe. He's usually depicted as one of Peter's close friends, adding to the social dynamics and plot developments.
Ned in the Spider-Man comics is a character who has different depictions. Sometimes he's just a classmate or friend, and in some versions, he might have a more significant role in the plot. It all depends on the particular comic run and the creative direction taken by the writers.
One of the best moments could be when Spider - Man first meets the Avengers. The look of shock or admiration on his face (or theirs) would be really interesting to read. It's a moment of two different worlds colliding.
The battle with the Green Goblin is also a very iconic part. The intense fight scenes and the personal connection between Peter Parker (Spider - Man) and Norman Osborn (Green Goblin) add a lot of depth to the story. Their relationship, both as friends in normal life and enemies as superhero and supervillain, is a key aspect of the Spider - Man canon.
One of the most romantic moments is when Peter Parker as Spider - Man saves Mary Jane Watson from falling. He swings down and catches her in his arms, and they share a look that shows their deep connection. It's a moment of both danger and love.
A great moment is when Spider - Man and Daredevil find themselves in a situation where they have to trust each other completely. Maybe they are trapped in a building rigged with bombs by a villain, and they have to rely on each other's skills to get out. It shows the depth of their relationship and how they can overcome differences when the situation demands it. Also, any time they have a rooftop chase together, with Spider - Man swinging and Daredevil using his acrobatic skills, is really cool and memorable.