Pokemon porn comic is neither legal nor ethical. It's a form of content that is considered offensive and against the law. Such material can cause harm and has no place in a civilized society.
Pikachu is a very likely candidate. It's Ash's most iconic Pokemon and has a deep bond with him. Whenever Ash is in trouble, Pikachu often steps up to protect him.
Ash could be a Pokémon trainer with a different starting point in this fanfiction. Born in 1987, by 1997 he might have already made a name for himself in local Pokémon battles. He could have a team of Pokémon that he rescued from difficult situations, like a Charmander that was abandoned by its trainer. His story could revolve around giving these Pokémon a second chance and proving that Pokémon don't need to be 'perfect' to be strong.
The impact of Ash's loss in the fanfiction could extend beyond just himself. His Pokémon might also feel demoralized. However, this could also be an opportunity for them to grow stronger together. Ash could start training more intensively, seek new training methods, or even try to catch new Pokémon to strengthen his team.
There shouldn't be and mustn't be such content. Pokemon is a beloved franchise for all ages, and pornographic comics related to it are completely unacceptable and against all norms of decency.
One popular type of Pokemon Ash and Pikachu fanfiction might be adventure - based. For example, Ash and Pikachu could embark on a journey to a new and mysterious region filled with undiscovered Pokemon species. They might face challenges like difficult terrains and powerful, previously - unseen Pokemon. In this fanfiction, Pikachu's electric powers could be enhanced in some unique way, and Ash would have to strategize differently to overcome the obstacles.