It could be the First Hokage, Hashirama. Naruto would be amazed by his powerful Wood - Style jutsu and his ability to create the village. He could learn about the original ideals behind the Hidden Leaf from Hashirama.
Shikamaru is another possibility. He is known for his strategic mind. As Hokage, he could use his intelligence to make wise decisions for the village. He may not have the brute strength of Naruto or Sasuke, but his ability to plan and analyze situations would be invaluable in leading Konoha.
Well, it depends on the specific fanfiction. Some fanfictions might explore alternate storylines where Naruto doesn't become the Hokage at all. Maybe he decides to pursue a different path in life, like focusing on being a teacher or an explorer. However, in a large number of fanfictions, he does achieve his goal of becoming the Hokage because it's such an iconic and desired outcome for fans who want to see his journey to the top in different ways.
Naruto would probably first assess the damage to the village. He would send out teams to check on the injured and start the process of getting the necessary supplies for the repairs. Then, he would call a meeting with the village council to discuss security measures to prevent future attacks like Pain's. He'd want to make sure that the village is well - defended and that they have a proper warning system in place.
Perhaps Naruto feels that the Hokage has been too strict or unfair in dealing with certain situations. Like if the Hokage didn't support Naruto's way of trying to bring peace and unity, which Naruto firmly believes in. This could lead to a growing resentment and eventually hatred.
In fanfiction, Naruto's rule as the 5th Hokage might be full of positive changes. He would probably focus on improving relationships between the different ninja clans in the village. He'd also likely invest a lot in training the new generation of ninjas, using his own experiences to teach them about perseverance and the importance of friendship.
His friends like Sakura and Shikamaru would surely support him. Sakura, with her medical skills, could be an important part of his regime, providing healthcare for the ninjas. Shikamaru, being intelligent, could offer strategic advice. Also, the younger generation of ninjas who have been inspired by Naruto would be his strong supporters, as they believe in his leadership and the new direction he could take the village in.
The Third Hokage's training might have introduced Naruto to more advanced jutsus. For example, he could have taught Naruto better control over his chakra, which is crucial for performing ninjutsu. This would allow Naruto to use his Rasengan more effectively and with less strain.
Perhaps a perk is the ability to shape the future of the ninja world. As Hokage, one can inspire the younger generation of ninjas. They can create new ninja academies or training programs. They also have the power to pardon or punish ninjas according to their deeds, which helps in maintaining law and order in the village.
Sasuke could also be a possibility for the 6th Hokage in the fanfic. He has grown stronger over the years and his unique perspective on the ninja world could bring new ideas to the leadership of the Hidden Leaf. He might start off as a controversial choice but prove himself through his actions in protecting the village and making tough decisions.