If I only want one chapter that proves why Liu Xian matters, should I jump to Chapter 221?

Chapter 112, "Entering Xingwu Continent And Space Talent", is the clearest early answer because it pushes Liu Yan into a new phase or setting. The chapter turns that into something concrete by moving from Wang Teng met the other five people from the Tiger Warrior team. to Lin Zhan and the rest of them were standing not far away..

Chapter 117, "The Second Option", is the clearest early answer because it turns Liu Yao's situation into a concrete plot event. The chapter turns that into something concrete by moving from It's a Derivative Fire Potion, don't worry, it's good for Fire... to It put the milk on the ground and floated to where the Fire-Toothed....

Chapter 519, "Masters Emerge, Rescuing Lu Changsheng! (4K)", is the clearest early answer because it turns Liu Yiyi's situation into a concrete plot event. The chapter turns that into something concrete by moving from Please be very careful, Ancestor." Huo Zhang knew that even with the... to After reading Dugu Aotian's letter, Liu Yiyi's eyes reddened, and she....

Chapter 36, "Who Can't Pass the Exam?", is the clearest early answer because it pushes Liu Yao into a new phase or setting. The chapter turns that into something concrete by moving from A magical profession rumored to be capable of judging how long it's... to Yeer!!!" Liu Yao opened his mouth, wanting to say something more when.... What makes it stick is that the chapter closes with Alas..., which gives Liu Yao a stronger narrative position and pushes the relationship tension onward.

Chapter 124, "Joyous Union Sect Supreme Elders (Weekend Extra)", is the clearest early answer because it turns Liu Yun's situation into a concrete plot event. The chapter turns that into something concrete by moving from Young Sect Leader!" A group of Joyous Union Sect Elders unleashed... to I want to torture him thoroughly and make his life worse than death."....

Chapter 414, "Challenge from the Holy Son of Yaochi! (4K)", is the clearest early answer because it turns Liu Mufeng's situation into a concrete plot event. The chapter turns that into something concrete by moving from Dad, Mom!" Liu Yiyi was somewhat excited; she had found that not only... to I have acquired a seventeenth-grade Nine-Colored Lily and am willing....

Chapter 246, "My Shuilu Yana is a Bit Old", is the clearest early answer because it turns Liu Yao's situation into a concrete plot event. The chapter turns that into something concrete by moving from Five minutes later, as Yaobao and Xiao Xunbao contentedly ate their... to In theory, with their Beast Taming combat skills being the best in....

Chapter 247, "Exchange Student", is the clearest early answer because it turns Liu Yao's situation into a concrete plot event. The chapter turns that into something concrete by moving from Shuilu Yana is less than a year old? to Fortunately, the only person who knew Shuilu Yana's whereabouts.... What makes it stick is that the chapter closes with Qiao Sang: "!!!, which gives Liu Yao a stronger narrative position and pushes the relationship tension onward.

Chapter 100, "Dao Palace Realm Level 9!", is the clearest early answer because Liu Yun finally turns buildup into a real advancement. The chapter turns that into something concrete by moving from It's almost done!" Lu Changsheng's aura was dramatically rising, and... to The presence of the Divine Thunder Exorcism Charm spread all around,....