Since the carbon-oxygen bond of Butanol was a polar bond, the electron negativity of the oxygen atom was greater than that of the carbon atom, so the carbon-oxygen bond was easy to break and an elimination reaction occurred. For example, the elimination reaction of 1-Butanol under the effect of concentrated sulfuric acid, the removal of the hydrogen atom from the alpha carbon atom, and the removal of the hydrogen atom from the beta carbon atom (also known as beta elimination reaction), the reaction produces 1-Buten and water, the reaction formula is CH3CH20H = CH3CH2CH = CH2 + H2O; 2-Butanol and concentrated sulfuric acid mixed together at 170 ° C will also undergo elimination reaction, forming CH2 = CH-CH2-CH3 + H2O or CH3CH = CH-CH3 + H2O; If the molecular dehydration reaction (reaction temperature is 140 degrees), the reaction formula is 2CH3-CH (CH)-CH2-CH3-concentrated sulfuric acid, 140 degrees-CH3-CH-OCHCH3/
Elemental sulfur can undergo an oxido-reduction reaction with concentrated sulfuric acid under heating conditions. Sulfur is oxided to sulfuric acid with a +6 valency, and concentrated sulfuric acid is reduced to nitrogen dioxide with a +4 valency. The reaction equation is: S +6HNO= heating = H ^SO+ 6NO ^+2H ^O. <a href="/?from=ask_words" style="color:red" target="_blank">Read more exciting novels for free</a>
Acetic anhydryride-concentrated sulfuric acid reaction (Liebermann-Burchard reaction) can be used to identify tripenoid and steroid side. The specific identification method was as follows: dissolve the sample in vinegar and add concentrated sulfuric acid-vinegar (1:20). If the final color was red or purple, it was triterpene soap. If the final color was blue-green, it was steroid soap. During the reaction process, color changes such as red → purple → blue → green → dirty green would occur in turn, and finally the color would fade. <a href="/?from=ask_words" style="color:red" target="_blank">Read more exciting novels for free</a>
At room temperature, concentrated sulfuric acid would have a slow corrosive effect on the polythene, and at 90 - 100 ° C, concentrated sulfuric acid would rapidly erode the polythene, causing it to be destroyed or decomposed. <a href="/?from=ask_words" style="color:red" target="_blank">Read more exciting novels for free</a>
1. 铁与浓硝酸反应: - 常温下铁在浓硝酸中会钝化,不反应。 - 加热时,若铁少量:\(Fe + 6HNO_{3}(浓)=\triangle=Fe(NO_{3})_{3}+3NO_{2}\uparrow+3H_{2}O\); - 若铁过量:\(Fe + 4HNO_{3}(浓)=\triangle=Fe(NO_{3})_{2}+2NO_{2}\uparrow+2H_{2}O\)。 2. 铁与稀硝酸反应: - 若铁少量:\(Fe + 4HNO_{3}(稀)=Fe(NO_{3})_{3}+NO\uparrow+2H_{2}O\); - 若铁过量:\(3Fe + 8HNO_{3}(稀)=3Fe(NO_{3})_{2}+2NO\uparrow+4H_{2}O\)。 <a href="/?from=ask_words" style="color:red" target="_blank">点击前往免费阅读更多精彩小说</a>
Taking the reaction of copper and sulfuric acid as an example, the reaction equation of concentrated sulfuric acid is: Cu +4HNO2 (concentrated) = Cu(NO2) 2 + 2NO2 ^+2H ^O, and the reduction product is NO2; The reaction equation of diluted sulfuric acid is: 3Cu +8HNO2 (diluted) = 3Cu(NO2) 2 + 2NO2 ^+4H ^O, and the reduction product is NO. The stronger the concentration of the acid, the stronger the ability to catalyze. This was reflected in the different reaction products. For example, the chemical equation of the reaction between concentrated sulfuric acid and carbon is: C+4HNO (concentrated) = CO2 ^+4NO2 ^+2H O; When dilute sulfuric acid and sulfur react, only S2 ions can be oxided into elemental sulfur, while when concentrated sulfuric acid and sulfur react, S2 ions can be further oxided into SO2 ions, such as 3dsS + 8HNO (diluted) = 3Cadr (NO2) 2 + 2NO2 ^+4H O + 3S. <a href="/?from=ask_words" style="color:red" target="_blank">Read more exciting novels for free</a>
The chemical equation for the reaction of cuprous chloride-concentrated sulfuric acid is: CuCl2 = H(CuCl2). There were also opinions that the reaction equation was cucl +2hci = h2(cucl3), and there were opinions that cuprous chlorideand concentrated sulfuric acid did not react. The reason why cuprous chloridecould be dissolved in concentrated sulfuric acid was because of the formation of a complex. The resulting solution should be colorless, but it often had a brown color when placed in the air. <a href="/?from=ask_words" style="color:red" target="_blank">Read more exciting novels for free</a>
The reaction rate of concentrated sulfuric acid with copper was faster than that of diluted sulfuric acid with copper. <a href="/?from=ask_words" style="color:red" target="_blank">Read more exciting novels for free</a>
Based on context alone The concentrated sulfuric acid could not be used for the preparation of hydrogen. Because hydrogen is an basic gas, concentrated sulfuric acid is volatile and acidic. When the two meet, a reaction will occur: <anno data-annotation-id ="cdf10000 - 4c00 - 4c10 - 4c10-a100-a11111110000"></anno>(the reaction phenomenon is to produce a large amount of white smoke), rather than being used to prepare hydrogen. The laboratory usually uses a solid mixture of lithium monium and lithium monium to heat up to prepare hydrogen. The reaction equation is [2NH4] Cl2 + CaCl2][2][3][4][4][5][6][7][8][8][9][9][ CaCl_{2}+2H_{2}O + 2NH_{3}\uparrow\)。 <a href="/?from=ask_words" style="color:red" target="_blank">Read more exciting novels for free</a>
When concentrated sulfuric acid was added to the solid of the sulfur dioxide, since the concentrated sulfuric acid had a strong oxidisation property and the sulfur dioxide had a reduction property, the two would undergo an oxidoreduction reaction. The reaction equation is [Na ^S + H ^SO (concentrated)= S + Na ^SO + H ^O]. The reaction phenomenon was the formation of sulfur, and at the same time, the formation of sulfuric acid and water. <a href="/?from=ask_words" style="color:red" target="_blank">Read more exciting novels for free</a>
In the reaction of preparing bromic ether, the first reaction was the reaction between concentrated sulfuric acid and the solution of the acid.(It can only produce bisulfuric acid, which can be referred to the reaction with NaCl2). The reaction equation is [H_{2} SO4}+ NaBr2 = NaHSO4 + Brr]. Then the formed [Brr] will react with alcohol. Under the conditions of concentrated sulfuric acid absorbing water and heating, the bromoether will be vaporized. The reaction equation is [Brr + CH3} CH2} 0H = CH3} CH2} Br2 + H2}O]. <a href="/?from=ask_words" style="color:red" target="_blank">Read more exciting novels for free</a>