One possible reason could be that he accidentally causes too much destruction during a mission. Maybe he loses control of his magic and wrecks an important place in the magical world, leading the guild to expel him as a form of punishment.
One possible reason could be that he accidentally causes a great deal of destruction during a mission that the guild can't overlook. Maybe he loses control of his dragon slayer magic and wrecks an important building or site, leading to his expulsion as a form of punishment.
It could be a rival wizard from another guild. This wizard might be jealous of Natsu's power and popularity within Fairy Tail. So, they fabricate evidence to get Natsu expelled, aiming to not only remove him as a competitor but also to create chaos within Fairy Tail. They could continue to be a thorn in Natsu's side as he tries to clear his name and get back to the guild.
One possible reason could be that he was wrongly accused of a serious crime within the guild. Maybe some powerful and influential members believed he was a threat and pushed for his banishment. For example, if there was a string of mysterious attacks and Natsu was framed as the culprit due to his often wild and uncontrollable nature in battle.
One possible plotline could be Natsu trying to prove his innocence. Maybe he was wrongly accused of a serious crime within the Fairy Tail guild, like endangering the lives of other guild members during a mission. He then sets out on a journey to find evidence that clears his name while also facing various challenges and enemies along the way.
One possible reason could be that he's framed for a crime he didn't commit. Maybe someone planted false evidence to make it seem like he was endangering the guild. Another reason might be that his power got out of control and the guild, fearing for the safety of its members, made the tough decision to kick him out.
In a fanfiction, there could be a situation where Lucy is forced to side with a group that Natsu is against. This would make Natsu see her as an enemy. Or perhaps there is a prophecy that Lucy is involved in that Natsu misinterprets as something bad. He might think she is a threat to the guild or his friends. Also, if there is a love triangle situation where Lucy chooses someone else over Natsu in a way that really hurts his feelings, that could be a reason for him to start hating her.
Perhaps they leave because of a disagreement within the guild. Maybe there's a new policy or a decision made by the guild master that they don't agree with. For example, if the guild decides to get involved in a war that they think is unjust, they might choose to leave rather than participate against their beliefs.
One possible reason could be a misunderstanding within the guild. Maybe some false information was spread about them, leading others in Fairy Tail to turn against them. Another reason might be a power struggle. If Natsu and Erza were becoming too powerful, some jealous members could have conspired to make it seem like they were betraying the guild. Or perhaps an outside force manipulated the situation to drive a wedge between them and the rest of Fairy Tail.
One reason could be that some writers might want to create a more complex or darker storyline. By having Natsu be hated, it adds conflict. Maybe they portray him as having made a big mistake that the other characters in the fanfic can't forgive.
One possible reason could be a misunderstanding. Maybe the other members of Fairy Tail misinterpret Natsu's actions as something harmful to the guild when in fact he has good intentions. For example, if Natsu accidentally destroys a valuable guild property while fighting a powerful enemy in the city, the guild might see it as irresponsible behavior and turn against him.