In a fanfic, Ichigo and Rukia's relationship could be developed by introducing emotional arcs. Maybe Rukia has a secret she's been keeping from Ichigo, and when it's revealed, it causes a rift between them. But through their shared love for their friends and the Soul Society, they eventually overcome it. Aizen could be the catalyst for this. His actions could force Rukia to reveal her secret. Meanwhile, Aizen's relationship with them could be developed by showing his envy or admiration for their relationship. He could try to break them apart because he sees their bond as a threat to his own plans, or he could be secretly longing for a relationship like theirs, which adds a new layer of complexity to his character.
A possible plot is that Aizen uses his powers to send Ichigo and Rukia into an alternate dimension. In this dimension, they have to rely on each other to survive and find a way back. Along the way, they encounter strange beings and challenges that test their limits. They might also discover secrets about Aizen's past or his true motives for sending them there. This could be a journey of self - discovery for both Ichigo and Rukia as they face these new and difficult situations together.
One idea could be that Aizen kidnaps them to use Ichigo's power and Rukia's knowledge of Soul Society for his own dark plans. He might want to study Ichigo's unique Hollow - Shinigami powers up close and use Rukia as a bargaining chip with Soul Society.
For Ichigo, his character could be developed by exploring his inner turmoil more deeply. Maybe he struggles with the idea of being half - human, half - Shinigami in a different way. As for Rukia, she could be developed by showing more of her past, like her early days in the Soul Society before she met Ichigo. This would give more depth to her character.
You can try searching on popular fanfic platforms like Fanfiction.net or Archive of Our Own. Just use the keywords 'Aizen - Obsessed Ichigo Rukia' in their search bars, and you might find relevant fanfics.
Aizen might be motivated by power. Ichigo has a very unique power set that Aizen may want to harness for himself. And Rukia, being from Soul Society, could be used as a way to gain information or leverage against Soul Society.
Rukia is also very popular. Her cool and composed nature, along with her powerful ice - based Zanpakuto abilities, make her stand out. Her backstory, being from the Soul Society and her connection to Ichigo, gives writers a lot to work with in terms of character development and plot.
One of the things that can make it interesting is the exploration of different character arcs. Aizen's obsession can be a catalyst for Ichigo and Rukia to grow in ways they might not have in the original story. It can also bring out different sides of their personalities. For example, Ichigo might become more determined to protect Rukia from Aizen, showing a deeper level of his loyalty. Rukia, on the other hand, could develop new strategies to deal with Aizen's threat, highlighting her intelligence and resourcefulness. Additionally, the fanfic could introduce new settings or concepts related to Aizen's obsession, such as alternate dimensions or new forms of power, which can keep readers engaged.
Maybe Aizen has created a false asylum as part of a new experiment. He lures Ichigo and Rukia into it, and they have to find a way to escape while also dealing with the illusions and traps Aizen has set up. In the process, they could learn more about Aizen's motives and past, and perhaps even find a way to defeat him once and for all.
Rukia, on the other hand, can be developed by exploring her cultural background more. Since she's from a different world, her reactions to the more 'lemon - like' or romantic situations could be influenced by her Soul Reaper upbringing. For example, she might initially be more reserved but then gradually open up as she falls deeper in love with Ichigo.
I'm not sure which specific one to recommend off - hand, but you can try looking on fanfiction.net. There are likely many 'Aizen Aslem Ichigo Rukia fanfic' there. You can search by tags like 'character relationships' or 'action - adventure' to find ones that might interest you.