Naruto himself could be a likely main character. Imagine if he ate the 'gasu gasu no mi'. He could combine his existing Rasengan techniques with the gas - based powers. For instance, he could create a Rasengan that is filled with a special gas that has different effects like paralysis or confusion on his enemies.
Sasuke could also be a great main character for this fanfiction. Given his intelligence and drive for power, if he got the 'gasu gasu no mi', he would find unique ways to use it. He might use the gas to enhance his Sharingan abilities, like using gas to distort the vision of his opponents so that his genjutsu becomes even more effective.
Well, a cool concept might be the character development of someone who eats the 'gasu gasu no mi' in the fanfiction. They could start off as a weak character but as they learn to master the powers of the fruit, they become a formidable force. Their personality might also change as they gain this new power, becoming more confident or even a bit power - hungry.
Naruto himself could be the main character. Imagine Naruto getting his hands on the Mochi Mochi no Mi. He would likely use his new powers in a very exuberant and creative way. His ability to make mochi could add a whole new dimension to his combat style, like using mochi to cushion his falls during his high - flying attacks or creating mochi - walls for defense.
Sakura could be a great main character. She's already a medical ninja, so having the Ope Ope no Mi would enhance her skills even more. She could use it to perform complex surgeries on the battlefield, saving more lives and becoming an even more important figure in the medical ninja community.
It could be a rogue ninja who also has a devil fruit power and wants to steal Naruto's Mera Mera no Mi ability. Maybe he has a water - based devil fruit power and sees Naruto's fire - based power as a threat to his own plans for domination.
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Sasuke. If Sasuke had an Akuma no Mi power, like the Goro Goro no Mi (Rumble - Rumble Fruit), it would make him even more formidable. He could use lightning - based attacks from his ninjutsu in combination with the electrical powers of the fruit. His already brooding and powerful character would become even more complex and dangerous.
In the Naruto - Star Wars crossover fanfiction, Anakin Skywalker could be a likely character to be betrayed. He has a complex personality and a lot of power. In the Star Wars canon, he was already betrayed by the Jedi Council in his view, which led him to the dark side. In a crossover, he could be further betrayed by a Naruto character who might misjudge him or be deceived by the Sith. Another could be Naruto himself. His trusting nature makes him vulnerable. A Star Wars villain could easily deceive him and then betray him when he is no longer useful.
Iruka sensei is another possibility. He is kind and nurturing, having already shown his care for Naruto when he was a student. As a baby daddy, he would be patient and dedicated to raising his child with good values and a love for learning.
Obviously Naruto would be one of the main characters. He's the protagonist of the original series and his power and will would be crucial in a doomsday scenario. Sasuke would also be likely, as his strength and his connection to Naruto are important elements. Sakura, with her medical skills, would also be a key character as she could be responsible for healing the injured during the doomsday chaos.