He might meet the Hokages again. They were his predecessors and he might seek their final words of advice or just to say goodbye. He could have a heart - to - heart with the First Hokage about how he has tried to uphold the values of the village. And with the Fourth Hokage, his father, it would be a very emotional reunion. He would tell his father how he has come to understand his sacrifice and how he has tried to live up to his legacy.
One emotional moment could be when Naruto is sharing his final words of wisdom with his friends. He might tell them to always keep believing in themselves and to protect the village at all costs.
There's a good chance he would meet Itachi. Itachi had a complex relationship with Naruto and played an important role in the overall story. In heaven, they could clear up any misunderstandings and Itachi could explain his actions more fully to Naruto, and Naruto could perhaps offer his forgiveness and understanding.
He would most likely meet his father, Minato Namikaze, and his mother, Kushina Uzumaki. These are the two main family members he never really got to know growing up.
Naruto could meet some young and upcoming Iwa ninja trainees. They might be curious about Naruto and his abilities from Konoha. These trainees could either look up to Naruto or be jealous of his fame, leading to various interactions. Also, there could be some old - timer Iwa ninjas who remember past events involving Konoha and have their own views on Naruto's presence in Iwa.
There's a possibility that Naruto meets some of the younger generation of shinobi in Suna. These new characters could be eager to learn from Naruto or challenge him to a friendly spar. He may also come across some of the elders in Suna who have their own stories and wisdom to share with Naruto.
He might meet his sensei, Jiraiya. They could have long talks about Naruto's growth as a ninja and Jiraiya could give him more wisdom from the afterlife perspective.
He might meet an old acquaintance who is also alone. They could share their stories and perhaps find some comfort in each other's company.
Naruto could also meet the previous Hokages in their prime. He could learn from them directly and perhaps even influence their decisions. For example, he might be able to convince the First Hokage to handle the Uchiha clan's situation differently, which could have a huge impact on the future (or in this case, the future that Naruto comes from).
Naruto would meet his younger self. This would be a really strange situation. He could also meet all the important shinobi from the past. For example, the First and Second Hokage. He might have a chance to learn from them directly, instead of just hearing about them in stories. Additionally, he could meet some of the characters who were only mentioned in passing in the original story but had a big influence in the past.
There could be new characters created specifically for this fanfiction. Maybe a young Suna shinobi who becomes Naruto's guide in Suna, showing him around the village and introducing him to the local way of life.