Probably Natasha Romanoff. Natasha is used to dealing with people who have a bit of an edge and a mysterious past, which Skye has. Natasha would be intrigued by Skye's skills and would likely reach out to her first.
In the fanfiction, Skye could be a key factor in bringing the Avengers closer together as a team. Her fresh perspective and determination could inspire the more jaded members like Clint Barton. She might also get caught up in the internal politics of the team, like when there are disagreements between Captain America and Iron Man. Skye could be the voice of reason that helps them see each other's points of view.
Skye would probably be cautious at first. She doesn't trust easily, especially when it comes to people who might be on the wrong side of the law. But she's also curious, so she would be interested in what the hackers have to offer in terms of knowledge and information.
She might befriend Iron Man first. Since he's into technology and Marinette is quite creative when it comes to making things. They could bond over creating new gadgets or improving existing ones.
In many Skye and Avengers fanfiction, the theme of redemption can be found. Maybe Skye has a past she's not proud of, and being with the Avengers gives her a chance to make up for it. Family is also a common theme. The Avengers can become like a family to Skye, and she has to find her place within this new 'family'. And of course, there's the theme of heroism. Skye and the Avengers are constantly striving to be heroes and save the day.
One great Skye and the Avengers fanfiction is the one where Skye joins the team early on. It shows how her hacking skills can be an asset to the Avengers in their missions. She helps them decrypt secret enemy messages and provides crucial intel.
Another popular trope is the 'romantic subplot'. Many fanfictions pair Skye with various Avengers. For instance, some pair her with Clint Barton. The stories often explore how their relationship develops over time, starting from initial attraction to deeper emotional bonds. This trope adds an extra layer of drama and emotion to the overall story.
Probably the other pups in the Paw Patrol would come to Skye's rescue. Rocky might use his recycling skills to build something useful to help in the search, like a makeshift ladder if Skye is stuck in a high place. Zuma could swim across any water bodies in the area where Skye is lost to reach her. And Rubble might dig through obstacles if needed.
With Coulson, their relationship could become more paternal. Since Skye can't express herself verbally, Coulson might feel more protective and take on a more hands - on role in guiding her. For Fitz - Simmons, they might become more inventive in finding ways to communicate with her, which could strengthen their friendship as they work together on new communication devices or methods. And with May, May could see Skye in a new light, respecting her even more for her ability to persevere without the use of speech.
A popular Skye and Avengers fanfiction is 'When Skye Met the Avengers'. This fanfic is interesting because it focuses on the first encounters between Skye and each of the Avengers. It shows how their different personalities clash and then gradually start to work together. It's full of humorous moments as well as some heart - warming scenes that show the growth of relationships among the characters.
You can try fanfiction websites like Archive of Our Own (AO3). It has a vast collection of fanfictions, and you can simply search for 'Skye knows the Avengers' in the search bar.