Ron Weasley and Demiurge could interact. Ron has a more laid - back and humorous personality, while Demiurge is a devious and intelligent character. Their interactions could range from Ron being a bit confused by Demiurge's complex plans to Demiurge trying to manipulate Ron for his own purposes, but Ron's loyalty to his friends might thwart Demiurge's attempts.
Hermione Granger and Albedo could also be characters that interact. Hermione is known for her intelligence and thirst for knowledge. Albedo is extremely intelligent as well in matters of strategy and magic in the Overlord world. They could exchange knowledge about their respective magic systems, like Hermione explaining the theory behind Transfiguration to Albedo.
Definitely Harry Potter and Optimus Prime. Harry is the hero in the wizarding world, and Optimus is the leader of the Autobots. They both have a strong sense of justice and would likely team up to face big threats. Another pair could be Hermione and Bumblebee. Hermione's intelligence could be used to understand the Transformers' technology, and Bumblebee's friendly nature would make them get along well.
Hermione and Betty would be likely to interact. Hermione's intelligence and thirst for knowledge could pair well with Betty's investigative nature. They could work together to solve a mystery that spans both the wizarding world and Riverdale.
Dumbledore could be another character. He is extremely powerful and wise. He might have some prior knowledge or intuition about Alduin's existence. He could interact with Alduin in a more diplomatic way, trying to understand Alduin's motives and perhaps find a way to co - exist peacefully if possible. Or, if Alduin proves to be a threat, Dumbledore would be one of the few who could stand up to him.
I think Ron Weasley would be one of the characters likely to interact. He's always up for an adventure, and the wildness of Neverland would appeal to him. Ginny Weasley could also be involved. She's brave and strong - willed. From Peter Pan's side, Tinker Bell might interact with the Hogwarts students. She's feisty and would be curious about these new arrivals with different kinds of magic. And of course, the Lost Boys would be eager to meet the wizards and witches from Hogwarts.
Harry Potter himself could interact with Sophie from Huntik. Harry is used to facing great challenges and having a strong sense of justice. Sophie, with her connection to the Titans, could find common ground with Harry in their fight against evil. They could learn from each other's worlds and work together to overcome a powerful dark force that threatens both universes.
Obviously, Harry Potter himself is very likely to interact with the Beast King. He has a natural inclination towards helping those in need and has a great sense of justice. Hermione Granger would also be a great character to interact with the Beast King. With her vast knowledge of magic and books, she could offer valuable insights about the Beast King's powers and history.
Harry Potter himself is a likely candidate. Given his heroic nature and penchant for getting involved in dangerous situations, he might be the one to first encounter Starscream. His experience with facing dark wizards could give him some skills to deal with the unpredictable Starscream.
Rebekah Mikaelson and Hermione would be likely to interact. Hermione is curious and intelligent, and she would be intrigued by Rebekah's different kind of magic. She would probably ask Rebekah a million questions about her vampire nature and the magic in her world. Rebekah, on the other hand, might be a bit annoyed at first but would come to respect Hermione's thirst for knowledge.
Probably Harry Potter and Edward Cullen. Since Edward is sort of the main character among the Cullens in a way, and Harry is the central figure in his world. They both have unique abilities and a sense of responsibility, so it makes sense for them to be the first to cross paths and start interacting.
Obviously, Harry Potter and Riddick would interact. Harry, being the main hero in his world, would be curious about Riddick's strange abilities and his rough - and - tumble way of life. Riddick, on the other hand, would likely be suspicious of Harry at first but then come to respect his magical powers.