Black Widow and Wolverine could have some friction too. Black Widow is a master spy and used to working in the shadows and using her wits. Wolverine is more of a brute - force fighter. She might try to manipulate him in some way, and he would not be happy about it at all, leading to some interesting power struggles between them.
Obviously, Rhodey and the Avengers members like Iron Man, Captain America, Thor, Hulk, etc. would be the main characters.
Obviously, Peter (presumably Peter Parker, Spider - Man) would be one of the main characters. And of course, the Avengers members like Iron Man, Captain America, Thor, Hulk, Black Widow, and Hawkeye are likely to be main characters too as they are the ones 'meeting' Peter.
Obviously, baby Peter would be one of the main characters. Among the rogue Avengers, it could be Captain America if he goes rogue in the story. Hawkeye might also be there as he has a family - like side and could be sympathetic to baby Peter. And Scarlet Witch could be involved too, with her powerful magic.
One interesting scenario could be Wolverine's reaction to the high - tech gadgets of the Avengers. Maybe he's initially skeptical but then sees their usefulness in battle.
Thor would be an interesting character to pair with Wolverine. Thor's god - like powers and Wolverine's tenacity would make for some epic battles. They could also have some great conversations about honor and sacrifice, coming from their very different backgrounds.
Doctor Strange and Ajak. Doctor Strange is well - versed in the mystic arts and Ajak has a lot of knowledge about the Eternals' history and their connection to the Celestials. Their knowledge areas could intersect, and they would likely be the first to start sharing information. Maybe Strange senses some strange energy related to the Eternals and approaches Ajak to find out more.
Iron Man and Robert Downey Jr. would likely have interesting interactions. Iron Man is known for his wit and charm, and Downey Jr. has a similar personality. They could exchange some clever banter and perhaps even discuss how Iron Man's character has evolved over the movies.
I think Hamilton and Captain America would be likely to form an alliance. They both have strong beliefs in justice and freedom. Captain America fought for his country in a different time, and Hamilton was a key figure in the American Revolution. They could understand each other's values and work together towards some common goals, whether it's about protecting the people or promoting certain ideals.
Definitely Iron Man and Jessica Jones. Iron Man is all about technology and being in control, while Jessica is more of a rough - around - the - edges detective. Their personalities would clash at first. Tony Stark might try to upgrade Jessica's equipment or give her some high - tech gadgets, but she would probably resist, leading to some really interesting exchanges between them.
Definitely Captain America. Their relationship has always been complex and full of different ideologies. Meeting future Tony would be a big moment for Steve as he would see how Tony has changed or what new ideas he brings. Also, Thor would likely interact with him. Thor, with his Asgardian knowledge and power, would be interested in the future technology Tony might bring. And of course, Black Widow. She's the master of espionage and would be curious about Tony's motives and what he's hiding from his future.