I'm not sure which novel you're referring to. Can you provide more background information and description? This way, I can better help you answer your questions.
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The young king himself is a main character. There may also be his advisers, some of whom could be good and some bad.
The main characters are Mufasa, Simba, Scar, and Nala. Mufasa is the king, Simba is his son, Scar is his brother, and Nala is Simba's mate.
There is likely to be the demon king - to - - be as the main character. And probably some supporting characters like his mentors, rivals, or friends.
The main character is surely the selfish demon king. There may also be some characters who oppose him, like brave knights or powerful mages.
In 'Maoyu - Archenemy & Hero', the main characters are the Demon King Mao and the Hero. Their relationship is complex, with both having their own agendas and trying to outwit each other while also having moments of cooperation. They are both strong - willed and intelligent, which drives the story forward.
The main character is usually the demon king or a potential demon king. There may also be teachers or other powerful demons at the academy.
I'm not sure specifically without reading it, but there's likely to be the demon king - to - - be as a main character, and perhaps some mentors or rivals.
In this type of novel, the most obvious main character is the selfish demon king. His personality and actions shape the story. However, there may also be other important characters. There could be a group of rebels, perhaps led by a charismatic leader, who are determined to overthrow the demon king. There might also be a love interest for one of the main characters, whether it's for the demon king (in a more complex and perhaps dark way) or for one of the good guys. And don't forget about the advisers or council members in the demon king's court. Some of them may play a role in either enabling his selfish behavior or trying to change his ways.
Since it's a 'demon king retry novel', the demon king is bound to be a central figure. There could also be characters who oppose the demon king, such as brave knights or powerful mages. And perhaps there are some neutral characters who get caught in the middle of the conflict between the demon king and his opponents. For example, ordinary villagers or merchants who are affected by the demon king's actions and the battles that ensue during his retry.