Sure, Deku takes on the role of a vigilante in the manga. It's a bold move that showcases his growth and the challenges he faces outside the conventional system of heroes.
A quirkless vigilante in My Hero Academia fanfiction would likely have a very different origin story compared to the typical hero. They could have been bullied or discriminated against because of their lack of a quirk. This would fuel their desire to prove themselves. They might start small, like stopping petty crimes in their neighborhood. As they gain more experience and confidence, they could take on bigger threats. Their lack of a quirk would also make them more relatable to the readers, as most of us are 'quirkless' in the real world. And their journey from being an unnoticed figure to a respected vigilante would be a great story arc.
No, it's not appropriate. Deku is a character with his own depth, goals, and story within the MHA universe. Fanfic should aim to explore his hero journey, his relationships in terms of mutual respect and support, not create content that focuses on inappropriate or disrespectful ideas like this.
He might cry a lot. Deku is very emotional, and being cheated on would be a very painful experience for him. He could also get angry, which is rare for him, but this situation would be so unjust that he might not be able to hold it in. He'd probably start to question his self - worth too, thinking that there was something wrong with him that made his partner cheat.
Deku might be initially shocked. He's used to Bakugou's aggression, but an actual injury is different. He could be in pain and disbelief at first. Then, he might try to downplay it, especially if he doesn't want to cause trouble for Bakugou, because Deku is generally a very forgiving character.
I don't really have a list of specific 'mha deku x boobs fanfic' as it might lead to some inappropriate or objectifying content. Instead, if you like Deku, you could search for fanfics that focus on his growth as a hero, his friendships, and his challenges. For example, there are many fics that explore his relationship with All Might or his classmates in a positive and meaningful way.
A villain like Shigaraki would likely be interested in the power levels in the MCU fanfiction. He's always looking for ways to increase his own power, and seeing the various powerful artifacts and abilities in the MCU might give him some ideas. He could think about how he could use similar things in his own plans to take over the MHA world.
If the MHA characters were to react to a Mastermind fanfiction, some would be more accepting than others. Characters like Ochaco might find it really exciting. She's a fan of the heroes herself, so seeing different takes in fanfiction would be like getting a new perspective on the MHA world. However, characters like Shoto, who are more reserved, might be a bit hesitant. He might need some time to process what he's reading. But overall, it would be a very interesting scenario as it would show how the characters view different interpretations of their world.