She would also be very determined to bring him back to the good side. Ladybug might search for a way to break whatever spell or influence has made Chat Noir evil. She could look for a special power - perhaps from another Miraculous or a magical item - that can reverse the change. And in the meantime, she has to be careful not to get hurt by Chat Noir while still trying to protect Paris.
One possible plot could be that Hawkmoth manages to finally corrupt Cat Noir. He might start causing chaos in Paris, attacking Ladybug instead of helping her. Ladybug would then be in a difficult situation, having to either try to save her partner or defeat him to protect the city.
It could still be Hawkmoth. Since he's always after the Miraculouses, he might find a way to turn Cat Noir evil and use him as a tool to finally get Ladybug's Miraculous. So Hawkmoth would be pulling the strings in the background while Cat Noir does his dirty work.
One possible plotline could be that he's tricked by a powerful villain. Maybe the villain uses some dark magic to cloud Chat Noir's judgment. For example, they could make him believe that Ladybug has betrayed him, so in his anger and confusion, he turns evil. He might start using his powers for wrongdoings instead of protecting Paris.
In an akumatized Ladybug fanfiction, the akuma might enhance her powers in unexpected ways. For example, her Lucky Charm could become a more powerful and unpredictable object. Her akumatized form might also have a darker and more menacing look, perhaps with a more aggressive fighting style. Writers could explore how the heroes and villains interact with this changed Ladybug.
In this 'Miraculous Ladybug Criminal Ladybug Fanfiction', there could be a lot of potential storylines. One possibility is that an external force is influencing Ladybug to commit crimes. It could be a new villain who has found a way to manipulate the Miraculous. This would create a great conflict as Ladybug has always been the symbol of good. Her friends and allies would be in shock and would have to find a way to stop her without hurting her. The story could also explore her internal struggle, as she might be aware of what she's doing but unable to stop herself.
A new villain could have a weapon that specifically targets Ladybug's powers. When she tries to use her yo - yo or her powers of creation, it backfires and causes her harm. This would force her to rely on her wits and Chat Noir more than ever. They would need to find a way to neutralize the weapon and heal Ladybug.
In a fanfiction, Ladybug could get hurt as a result of a trap set by Hawkmoth. He might have studied her fighting patterns and set up a situation where she is lured into a place full of obstacles that cause her physical harm. This would not only test her physical strength but also her mental resilience as she tries to figure out how to escape and continue her fight against evil.
Well, it's unique because it flips the whole concept of Ladybug on its head. Instead of being the hero, she's the criminal. It goes against the normal narrative we know from the show.
The novelty of seeing a usually heroic character like Ladybug turn bad is a big draw. It flips the script on the typical story. Instead of saving the day, she could be causing trouble, which makes for an exciting change.