Gon in fanfiction can be very single - minded in his pursuit of goals, just like in the original. He might be a bit more naive at times, which can lead to interesting plot twists. Killua is often portrayed as having a complex emotional side. He struggles with his past as an assassin and his loyalty to Gon. His cool exterior may crack in some fanfictions, showing his true feelings.
Toge Inumaki is important too. His special cursed speech ability makes him stand out. Also, the principal of the school, Masamichi Yaga, is likely to be important as he is in a position of authority and has an influence on Gojo and the other students. There could be other characters like the members of different clans that also play roles in the complex web of the story.
In a Naruto world fanfic, Killua would bring a whole new dynamic. He has a dark past as an assassin which could either make him a feared or respected figure. His family's training has made him physically and mentally tough. In battles, he could use his electricity - based attacks in creative ways against ninjas. But he would have to learn about things like jutsus and the ninja villages. Also, his relationship with Gon in the HxH world was important for his character development, and in the Naruto world, he might find a similar bond with a fellow shinobi, which could change his perspective on things.