Rukia would probably be both amazed and a bit worried. Amazed at the new power Ichigo has, but worried about how it might change him. Chad would see it as a natural progression of Ichigo's power and be supportive. Orihime might be a bit scared at first, but then she would see the good in Ichigo's new form and try to encourage him.
Rukia would probably be one of the first to be both shocked and amused. She might tease Ichigo a bit at first but then quickly get serious about helping him. Chad would be very accepting and offer his protection as usual. Uryu might be a bit more skeptical at first, thinking it's some kind of new Hollow trick. Orihime would be very empathetic and try to make Ichigo feel comfortable in his new form, maybe even offer to make some new clothes for him to fit his new body.
Rukia would probably be very suspicious right away. She knows Ichigo well and would notice the strange changes in his behavior. She might try to confront him and figure out what's wrong.
The Soul Reapers in the Soul Society would see Ichigo as a major threat. They would likely mobilize their forces to either capture or eliminate him. Captains like Byakuya would be disappointed as he had come to respect Ichigo to some extent, and now would see him as a traitor.
Orihime would probably be over - the - moon excited. She's always been a kind - hearted and emotional person. She would immediately start knitting baby clothes or making cute little charms for the baby. Chad would be very supportive as well. He would offer his strength to protect Rukia during her pregnancy. Uryu might be a bit more reserved at first, but deep down he would be happy for them. He might use his Quincy skills to create some sort of protective item for the baby.
Chad would be a very protective and gentle presence. He would be like an uncle to the baby, always ready to pick the baby up and play with it. His calm and strong nature would make the baby feel safe.
Rukia would be extremely shocked and disappointed. She has always seen Ichigo as a force for good, and seeing him side with Aizen, who is the main antagonist, would be a huge blow to her. She might try to talk Ichigo out of it at first, and if that fails, she could become his enemy.
At the start, Ichigo would be defiant. He would not show any fear in front of Aizen. He might taunt Aizen, trying to get him to reveal his true intentions. As time goes on, he would start to feel a sense of isolation, but this would only strengthen his resolve. He would use his inner Hollow powers more freely, as he has no other option. He would also be constantly thinking about ways to turn the tables on Aizen and escape, and would be ready to take on any challenges that come his way during his captivity.
The characters in DxD would be quite shocked at first. Ichigo's appearance and his powers are so different from what they are used to. For example, Rias Gremory would probably be intrigued by Ichigo. She might try to form an alliance with him, seeing his potential as a powerful ally. Issei, being the main character in DxD, would likely be both jealous and in awe of Ichigo's abilities, and might challenge him at first but then learn from him over time.
In a more complex way, their relationship could be one of growth. Unohana's calm and collected nature could influence Ichigo to be more patient. At the same time, Ichigo's bold and fearless attitude could inspire Unohana to be more adventurous in her approach to things. This mutual influence could lead to a deep and meaningful relationship that evolves as they face different challenges together in the fanfiction.
Korra would likely be very cautious at first. She's used to dealing with powerful opponents, but Hollow Ichigo's otherworldly nature would be something new. She might try to communicate with him, but if he showed aggression, she'd be ready to fight. Asami would probably be more strategic, trying to figure out his weaknesses. Mako and Bolin would be a bit more intimidated. Mako might use his lightning - bending as a first line of defense, while Bolin would be thinking of ways to use his earth - bending to either trap or slow down Hollow Ichigo.